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1.
In this study, parenchyma cellulose, which was extracted from maize stalk pith as an abundant source of agricultural residues, was applied for preparing cellulose nanoparticles (CNPs) via an ultrasound-assisted etherification and a subsequent sonication process. The ultrasonic-assisted treatment greatly improved the modification of the pith cellulose with glycidyltrimethylammonium chloride, leading to a partial increase in the dissolubility of the as-obtained product and thus disintegration of sheet-like cellulose into nanoparticles. While the formation of CNPs by ultrasonication was largely dependent on the cellulose consistency in the cationic-modified system. Under the condition of 25% cellulose consistency, the longer sono-treated duration yielded a more stable and dispersible suspension of CNP due to its higher zeta potential. Degree of substitution and FT-IR analyses indicated that quaternary ammonium salts were grafted onto hydroxyl groups of cellulose chain. SEM and TEM images exhibited the CNP to have spherical morphology with an average dimeter from 15 to 55 nm. XRD investigation revealed that CNPs consisted mainly of a crystalline cellulose Ι structure, and they had a lower crystallinity than the starting cellulose. Moreover, thermogravimetric results illustrated the thermal resistance of the CNPs was lower than the pith cellulose. The optimal CNP with highly cationic charges, good stability and acceptable thermostability might be considered as one of the alternatively renewable reinforcement additives for nanocomposite production. 相似文献
2.
研究玉米淀粉接枝聚丙烯酸酯共聚物的各级结构,主要探讨去除均聚物和玉米淀粉侧链的方法。发现以环己烷为溶剂,用索氏萃取法除去均聚物比用苯萃取法时间短、效果好;用HCl酸解法除去淀粉侧链比用HClO4氧化法简单实用。用红外光谱进一步验证了各级结构的官能团,证实了所合成的共聚物是玉米淀粉接枝聚丙烯酸酯共聚物。 相似文献
3.
重金属Pb2+对玉米苗生长的影响 总被引:11,自引:1,他引:10
以水栽培的玉米幼苗为材料,用不同浓度的醋酸铅溶液处理后,分别在第10天、第20天、第30天对玉米苗的根、茎、叶分别进行Pb^2+含量测定。分析结果:Pb^2+在玉米体内的分布表现为根〉叶〉茎;玉米中的叶绿素含量均降低;随着Pb^2+浓度的增大,玉米细胞的膜透性表现根〉叶〉茎依次升高;Pb^2+对玉米的伤害率的大小表现为根〉叶〉茎。该实验为进一步研究农作物对重金属Pb^2+的耐性和重金属Pb^2+在农作物体内的分布提供了可参考的数据。 相似文献
4.
Bonnie R. Hames Steven R. Thomas Amie D. Sluiter Christine J. Roth David W. Templeton 《Applied biochemistry and biotechnology》2003,105(1-3):5-16
New, rapid, and inexpensive methods that monitor the chemical composition of corn stover and corn stover-derived samples are
a key element to enabling the commercialization of processes that convert stover to fuels and chemicals. These new techniques
combine near infrared (NIR) spectroscopy and projection to latent structures (PLS) multivariate analysis to allow the compositional
analysis of hundreds of samples in 1 d at a cost of about $10 each. The new NIR/PLS rapid analysis methods can also be used
to support a variety of research projects that would have been too costly to pursue by traditional methods. 相似文献
5.
Measurement of rheological properties of corn stover suspensions 总被引:1,自引:0,他引:1
Corn stover is currently being evaluated as a feedstock for ethanol production. The corn stover suspensions fed to reactors
typically range between 10 and 40% solids. To simulate and design bioreactors for processing highly loaded corn stover suspensions,
the rheologic properties of the suspension must be measured. In systems with suspended solids, rheologic measurements are
difficult to perform owing to settling in the measurement devices. In this study, viscosities of corn stover suspensions were
measured using a helical ribbon impeller viscometer. A calibration procedure is required for the impeller method in order
to obtain the shear rate constant, k, which is dependent on the geometry of the measurement system. The corn stover suspensions are described using a power law
flow model. 相似文献
6.
Microextraction by packed sorbent liquid chromatography with time‐of‐flight mass spectrometry of triazines employing a molecularly imprinted polymer† 下载免费PDF全文
Felipe Nascimento Andrade Álvaro José Santos‐Neto Fernando Mauro Lanças 《Journal of separation science》2014,37(21):3150-3156
Molecularly imprinted polymers for the determination of triazines were synthesized by precipitation using atrazine as template, methacrylic acid as functional monomer, ethylene glycol dimethacrylate as crosslinker, and 2,2′‐azobisisobutrynitrile as initiator. The polymers were characterized by infrared spectroscopy and scanning electron microscopy and packed in a device for microextraction by packed sorbent aiming for the preconcentration/cleanup of herbicides, such as atrazine, simazine, simetryn, ametryn, and terbutryn in corn samples. Liquid chromatography coupled with time‐of‐flight mass spectrometry was used for the separation and determination of the herbicides. The selectivity coefficient of molecularly imprinted polymers was compared with that of nonimprinted polymer for the binary mixtures of atrazine/propanil and atrazine/picloram, and the values obtained were 15.6 and 2.96, respectively. The analytical curve ranged from 10 to 80 μg/kg (r = 0.989) and the limits of detection and quantification in the corn matrices were 3.3 and 10 μg/kg, respectively. Intra‐ and interday precisions were < 14.8% and accuracy was better than 90.9% for all herbicides. Polymer synthesis was successfully applied to the cleanup and preconcentration of triazines from fortified corn samples with 91.1–109.1% of recovery. 相似文献
7.
NaN_3对玉米萌发过程中超弱光子辐射的影响 总被引:1,自引:0,他引:1
为了解读植物种子萌发过程中超弱光子辐射信息的生物学意义,采用呼吸抑制剂NaN3处理萌发玉米种子,跟踪测量和分析了玉米种子萌发过程中超弱光子辐射中自发光子辐射和外界光诱导的延迟光子辐射的变化规律,同时研究了萌发玉米种子鲜质量的变化.结果发现,NaN3同步抑制了萌发玉米自发光子辐射和鲜质量的增长,造成萌发玉米延迟光子辐射的初始光子数和延迟光子辐射积分强度大幅度降低,相干时间减小.机理分析表明,NaN3对呼吸代谢电子传递链的抑制造成的自由基反应减弱是萌发玉米自发光子辐射减小的原因,自发光子辐射强度可以作为玉米萌发状态的信号,延迟光子辐射动力学参数的大小可以表征萌发玉米呼吸代谢的强弱,相干时间是种子细胞组织序性的量度,通过对萌发种子超弱光子辐射的采集和分析可以实现对萌发种子细胞代谢和功能状态变化的灵敏和无损检测. 相似文献
8.
随着化石能源的日益短缺,可再生木质生物质资源的利用越来越受到重视,常压液化技术是生物质资源高效利用的主要方式之一。利用单因素方法,探讨液化温度、复配液化剂二甘醇(DEG)与1,2-丙二醇(PG)的混合比、液固比、催化剂磷酸的用量、反应时间等因素对玉米秸秆液化得率的影响,以便优化其液化工艺;然后采用热重分析仪(TGA)、气相色谱-质谱技术(GC-MS)和核磁共振(NMR)技术对此优化条件下所得生物油的挥发降解特性和主要组成成分进行了检测探讨。分析表明,玉米秸秆液化时优化工艺参数为:液化温度170 ℃,液化剂DEG与PG混合比1∶2,液固比5∶1,H3PO4用量10%,反应时间45 min;此时玉米秸秆液化得率高至99.50%。TGA结果表明,此条件下所得生物油含有80%以上碳数小于25的化合物,热解后最终残炭量约为15%。GC-MS表明,可以检测出此生物油中含有的39种有机物,其中,醇类有机物的含量最多,酚类有机物的含量次之,它们相对含量依次是70.70%和25.63%,其还含有一定量的有机酸(2.80%)、醚类(0.64%)、酯类(0.10%)和酮类(0.13%)等有机物;其组分十分复杂,高含氧量,稳定性较差。1H-和13C-NMR分析表明,不同化学位移δ与生物油中不同类型的质子和碳原子相对应,明确生物油中不同类型H和C的分布,有利于对其分子结构进行深入探讨。这些研究为非木材生物质高效液化条件的选择及液化产物制备化学品和生物燃油给予理论基础与应用支持,促进了生物质资源的有效转化利用及其生物质基产品的开发。 相似文献
9.
10.
Mild and effective pretreatments are essential to deconstruct lignocellulosic biomass so as to reuse cellulose content for value-added products. In this study, sequential multimode-ultrasound and microwave with natural ternary deep eutectic solvent (NATDES) pretreatments were used to deconstruct corn straw and optimized factors such as NATDES, ultrasonic, and microwave parameters. Results indicated that the ultrasound-NATDES or microwave-NATDES pretreatment could remove 37.86% and 52.36% lignin, respectively. When using sequential multimode-ultrasound and microwave assisted NATDES pretreatment, the delignification efficiency increased to 61.50%, and the cellulose content increased from 34.70% to 76.08%. In addition, the delignification of sequential multimode-ultrasound and microwave assisted NATDES pretreatment (under the mild conditions of microwave heating at 60 °C and 60 min) increased to 57.39%, and the cellulose content increased to 59.98%, too. This highlighted the effect of the combined ultrasound and microwave technology. Finally, the microstructural changes of mercury intrusion porosimeters, scanning electron microscopy, thermogravimetric, X-ray diffraction and Fourier transform mid-infrared spectroscopy were conducted to confirm the effectiveness of this method to deconstruct corn straw. A mechanism of the deconstruction of corn straw biomass in NATDES with the assistance of the sequential multimode-ultrasound and microwave heating was proposed. This research could open a window for future use of biomass energy by deconstructing lignocellulosic biomasses using environmentally friendly pretreatment methods. 相似文献